英文MSDS(Material Safety Data Sheet)对化合物sodium ferrocyanide的详细说明如下:
1. Identification of the substance/mixture and of the company/undertaking:
- Product name: Sodium ferrocyanide
- Synonyms: Yellow prussiate of soda, sodium hexacyanoferrate(II)
- CAS No.: 14434-22-1
- EC No.: 237-081-9
- Manufacturer/supplier: [manufacturer/supplier name and contact information]
2. Hazards identification:
- Classification of the substance or mixture: Harmful if swallowed. Causes severe skin burns and eye damage.
- Label elements:
- Signal word: Danger
- Hazard statements:
- H302: Harmful if swallowed.
- H314: Causes severe skin burns and eye damage.
- Precautionary statements:
- P260: Do not breathe dust/fume/gas/mist/vapors/spray.
- P264: Wash contaminated skin thoroughly after handling.
- P270: Do not eat, drink or smoke when using this product.
- P280: Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
- P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
3. Composition/information on ingredients:
- Chemical characterization: Sodium ferrocyanide dihydrate (Na4Fe(CN)6•2H2O)
- CAS No.: 14434-22-1
- EC No.: 237-081-9
- % concentration: [manufacturer/supplier to provide]
4. First aid measures:
- General advice: Move out of dangerous area. Consult a physician.
- Inhalation: Remove from exposure, rest and keep warm. If symptoms persist, call a physician.
- Skin contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing. Call a physician if irritation develops or persists.
- Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately.
- Ingestion: Rinse mouth. Do NOT induce vomiting.
5. Firefighting measures:
- Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
- Special hazards arising from the substance or mixture: May release toxic cyanide gas when heated to decomposition.
- Advice for firefighters: Wear self-contained breathing apparatus and protective clothing.
6. Accidental release measures:
- Personal precautions, protective equipment and emergency procedures: Wear appropriate personal protective equipment (see section 8). Evacuate personnel to safe areas. Avoid dust formation.
- Environmental precautions: Do not allow to enter drains or watercourses.
- Methods and materials for containment and cleaning up: Sweep up and shovel into suitable containers for disposal.
7. Handling and storage:
- Precautions for safe handling: Avoid formation of dusts. Do not breathe dust. Do not eat, drink or smoke when using this product. Wash hands and face thoroughly after use.
- Conditions for safe storage: Store in a cool, dry, well-ventilated place. Keep container tightly closed.
8. Exposure controls/personal protection:
- Occupational exposure limits: [manufacturer/supplier to provide]
- Appropriate engineering controls: Use local exhaust ventilation if there is risk of inhalation of dusts.
- Personal protective equipment:
- Respiratory protection: Use appropriate respiratory protection if ventilation is inadequate.
- Hand protection: Wear protective gloves.
- Eye protection: Wear safety glasses or goggles.
- Skin and body protection: Wear suitable protective clothing.
9. Physical and chemical properties:
- Appearance: Yellow crystalline powder.
- Odor: Odorless.
- Melting point/freezing point: Decomposes at 435°C (815°F).
- Density: 1.458 g/cm³
- Solubility: Soluble in water.
10. Stability and reactivity:
- Reactivity: Stable under normal conditions.
- Chemical stability: Stable under recommended storage conditions.
- Possibility of hazardous reactions: May release toxic cyanide gas when heated to decomposition.
- Conditions to avoid: Avoid contact with acids and oxidizing agents.
- Incompatible materials: Acids, oxidizing agents.
- Hazardous decomposition products: Cyanide gas.
11. Toxicological information